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We report precise radial velocity (RV) observations of HD 212657 (= K2-167), a star shown by K2 to host a transiting sub-Neptune-sized planet in a 10 d orbit. Using Transiting Exoplanet Survey Satellite (TESS) photometry, we refined the planet parameters, especially the orbital period. We collected 74 precise RVs with the HARPS-N spectrograph between August 2015 and October 2016. Although this planet was first found to transit in 2015 and validated in 2018, excess RV scatter originally limited mass measurements. Here, we measure a mass by taking advantage of reductions in scatter from updates to the HARPS-N Data Reduction System (2.3.5) and our new activity mitigation method called CCF Activity Linear Model (CALM), which uses activity-induced line shape changes in the spectra without requiring timing information. Using the CALM framework, we performed a joint fit with RVs and transits using exofastv2 and find Mp = $6.3_{-1.4}^{+1.4}$  $\, M_{\hbox{$\oplus $}}$ and Rp = $2.33^{+0.17}_{-0.15}$  $\, R_{\hbox{$\oplus $}}$, which places K2-167 b at the upper edge of the radius valley. We also find hints of a secondary companion at a ∼22 d period, but confirmation requires additional RVs. Although characterizing lower mass planets like K2-167 b is often impeded by stellar variability, these systems especially help probe the formation physics (i.e. photoevaporation, core-powered mass-loss) of the radius valley. In the future, CALM or similar techniques could be widely applied to FGK-type stars, help characterize a population of exoplanets surrounding the radius valley, and further our understanding of their formation.

 

Rocky planets are common around other stars, but their atmospheric properties remain largely unconstrained. Thanks to a wealth of recent planet discoveries and upcoming advances in observing capability, we are poised to characterize the atmospheres of dozens of rocky exoplanets in this decade. The theoretical understanding of rocky exoplanet atmospheres has advanced considerably in the last few years, yielding testable predictions of their evolution, chemistry, dynamics, and even possible biosignatures. We review key progress in this field to date and discuss future objectives. Our major conclusions are as follows: ▪ Many rocky planets may form with initial H 2 –He envelopes that are later lost to space, likely due to a combination of stellar UV/X-ray irradiation and internal heating. ▪ After the early stages of evolution, a wide diversity of atmospheric compositions is expected as a result of variations in host star flux, atmospheric escape rates, interior exchange, and other factors. ▪ Observations have ruled out both the presence of H 2 -dominated atmospheres on several nearby rocky exoplanets and the presence of any thick atmosphere on one target. A more detailed atmospheric characterization of these planets and others will become possible in the near future. ▪ Exoplanet biosphere searches are an exciting future goal. However, reliable detections for a representative sample of planets will require further advances in observing capability and improvements in our understanding of abiotic planetary processes. 

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.